Raman spectra of pyridine adsorbed at a silver electrode

M Fleischmann, PJ Hendra, AJ McQuillan - Chemical physics letters, 1974 - Elsevier
Raman spectroscopy has been employed for the first time to study the role of adsorption at
electrodes. It has been possible to distinguish two types of pyridine adsorption at a silver
electrode. The variation in intensity and frequency of some of the bands with potential in the
region of the point of zero charge has given further evidence as to the structure of the
electrical double layer; it is shown that the interaction of adsorbed pyridine and water must
be taken into account.